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Browse Journals & Magazines > Review of Scientific Instrume ...> Volume:79 Issue:4 Help

Measurements of NOx, acyl peroxynitrates, and NOy with automatic interference corrections using a NO2 analyzer and gas phase titration

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2 Author(s)
Hargrove, James ; Department of Chemistry, University of California, Riverside, California 92521, USA ; Zhang, Jingsong

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NO2 analyzers are much more valuable if they can also measure NO since the two (NO+NO2=NOx) are often found together. NO can be quantitatively converted to NO2 by reaction with ozone and subsequent thermal decomposition of the N2O5 that may form from further oxidation. The conversion of NO, along with decomposition of N2O5 and removal of the remaining unreacted ozone with a heated chamber, allows for quantitative determination of NOx using a NO2 analyzer and the determination of decomposed acyl peroxynitrates. Ambient tests are performed to demonstrate these methods.

Published in:
Review of Scientific Instruments  (Volume:79 ,  Issue: 4 )

Date of Publication: Apr 2008

Page(s):
046109 - 046109-3
ISSN :
0034-6748
Digital Object Identifier :
10.1063/1.2908432
Product Type:
Journals & Magazines
Date of Current Version :
18 June 2009
Issue Date :
Apr 2008

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