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Formation of silver nanoparticles under anodic surface of tellurite glass via thermal poling-assisted ion implantation across solid-solid interface

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5 Author(s)
Murai, Shunsuke ; Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan ; Fujita, Koji ; Kawase, Sonoko ; Ukon, Sakiko
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We have developed a technique by which poling and ion implantation in solid state are simultaneously accomplished. The technique has been applied to 2Ag2O∙3Na2O∙25ZnO∙70TeO2 (in mol %) glass. The glass is sandwiched by two cover glasses containing Na+ and then the thermal poling is carried out. We have accidentally found that Ag nanoparticles are selectively precipitated in the vicinity of the anode-side glass surface. X-ray photoelectron spectroscopy reveals that the glass composition of the anode-side glass surface becomes rich in Na+ after the thermal poling, which is caused by the Na+ implantation from the cover glass at the anode side.

Published in:

Journal of Applied Physics  (Volume:102 ,  Issue: 7 )