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Growth and interface of HfO2 films on H-terminated Si from a TDMAH and H2O atomic layer deposition process

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3 Author(s)
Hackley, Justin C. ; Department of Physics, University of Maryland Baltimore County (UMBC), Baltimore, Maryland 21250 ; Demaree, J.Derek ; Gougousi, Theodosia

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HfO2 thin films have been deposited by an atomic layer deposition (ALD) process using alternating pulses of tetrakis(dimethyl)amino hafnium and H2O precursors at a substrate temperature of 200–325 °C. The initial stage of film growth on OH- and H-terminated Si(100) surfaces is investigated using Rutherford backscattering spectrometry (RBS), x-ray photoelectron spectroscopy (XPS), and spectroscopic ellipsometry (SE). The authors observe an initial growth barrier on the Si–H surface for the first approximately four process cycles, where film growth is more efficient on the OH-terminated surface. Both starting surfaces require about 15 cycles to reach a steady growth rate per cycle, with the OH-terminated surface displaying a slightly higher growth rate of 2.7×1014 Hf/cm2 compared to 2.4×1014 Hf/cm2 for Si–H. Combining the RBS and SE data we conclude that the films deposited on the OH-terminated surface are denser than those deposited on the Si–H surface. Angle-resolved XPS measurements reveal the formation of an ∼8 Å interfacial layer after four ALD cycles on the H-terminated surface for a deposition temperature of 250 °C, and transmission electron microscopy verifies that the thickness of the interfacial layer does not change substantially between the 4th and the 25th process cycles. The interfacial layer appears to depend weakly on the deposition temperature from 200 to 325 °C, rang- - ing from 6.9 to 8.4 Å.

Published in:

Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films  (Volume:26 ,  Issue: 5 )

Date of Publication:

Sep 2008

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