The tube number density of aligned carbon nanotubes (CNTs) grown over the nanoporous anodic aluminum oxide (AAO) template can be directly controlled by adjusting the CH4/H2 feed ratio during the CNT growth. We ascribe the variation of the tube density as a function of the CH4/H2 feed ratio to the kinetic competition between outgrowth of cobalt-catalyzed CNTs from the AAO pore bottom and deposition of the amorphous carbon (a-C) overlayer on the AAO template. A pore-filling ratio of 18% to 82% for the nanotubes overgrown out of nanopores on the AAO template can be easily achieved by adjusting the CH4/H2 feed ratio. Enhanced field emission properties of CNTs were obtained by lowering the tube density on AAO. However, at a high CH4 concentration, a-C by-product deposit on the CNT surface can degrade the field emission property due to a high energy barrier and significant potential drop at the emission site.
Published in:
Applied Physics Letters
(Volume:86
,
Issue:
12
)
Date of Publication:
Mar 2005
- Page(s):
-
123111
-
123111-3
- ISSN :
-
0003-6951
- Digital Object Identifier :
-
10.1063/1.1886260
- Product Type:
-
Journals & Magazines
- Date of Current Version :
-
18 June 2009
- Issue Date :
-
Mar 2005