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High-performance polymer light-emitting diodes fabricated with a polymer hole injection layer

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5 Author(s)
Gong, X. ; Institute for Polymers and Organic Solids, University of California at Santa Barbara, Santa Barbara, California 93106 ; Moses, D. ; Heeger, A.J. ; Liu, S.
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Enhanced luminance (L) and luminous efficiency (LE) of polymer light-emitting diodes (PLEDs) is demonstrated using poly(bis(tetraphenyldiamino)biphenyl-perfluorocyclobutane), poly(BTPD-Si-PFCB), as the hole injection layer. The monomer is cast directly onto the indium-tin-oxide anode and thermally polymerized in situ. Hole injection from poly(BTPD-Si-PFCB) into the “super yellow” derivative of poly(phenylene vinylene) and into several blue-emitting polymers is comparable to or better than that from poly(ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSSA). With poly(BTPD-Si-PFCB) as the hole injecting layer into “super yellow,” the performance is identical to that obtained with PEDOT:PSSA (LE≈8 cd/A with little fall-off, even at L≫104cd/m2). © 2003 American Institute of Physics.

Published in:

Applied Physics Letters  (Volume:83 ,  Issue: 1 )

Date of Publication:

Jul 2003

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