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Nanodomains of pyrochlore formed by Ti ion implantation in yttria-stabilized zirconia

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4 Author(s)
Zhu, S. ; Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109-2104 ; Zu, X.T. ; Wang, L.M. ; Ewing, R.C.

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The microstructural evolution of a single crystal of yttria-stabilized zirconia (YSZ) implanted with Ti has been studied by cross-sectional transmission electron microscopy (TEM). The implantation of 180 keV Ti ions to a dose of 1×1017 ions/cm2 was completed at room temperature. After annealing at 1100 °C in an Ar atmosphere for 2 h, a phase transition from the fluorite structure of ZrO2 to an isometric pyrochlore structure-type, A2B2O7, occurred due to cation ordering. High-resolution TEM revealed nanodomains of pyrochlore, Y2(TixZr1-x)2O7, with a≅10.24±0.05 Å. The nanodomains of the pyrochlore phase, embedded within the YSZ fluorite substrate, occurred in a depth range from 45 to 105 nm below the surface, which corresponds to Ti concentrations from ∼10 to ∼15 at. %. The nanoscale pyrochlore precipitates and the YSZ matrix have a completely coherent orientation. © 2002 American Institute of Physics.

Published in:

Applied Physics Letters  (Volume:80 ,  Issue: 23 )