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Atomic force microscope manipulation of gold nanoparticles for controlled Raman enhancement

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3 Author(s)
Tong, Lianming ; Center for Nanoscale Science and Technology, Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China ; Zhu, Tao ; Zhongfan Liu

Your organization might have access to this article on the publisher's site. To check, click on this link:http://dx.doi.org/+10.1063/1.2822418 

We report on the controlled manipulation of two, three and four gold nanoparticles (AuNPs) using an atomic force microscope (AFM) for use as surface-enhanced Raman scattering substrates. For each arrangement, the interparticle electromagnetic (EM) coupling between adjacent AuNPs is studied at different polarization angles. It is found that the strength of EM coupling strongly depends on the arrangement of the AuNPs. In particular, the highest enhancement and the most pronounced polarization dependence is found for linear arrangement of closely spaced particles. Our results show that AFM manipulation has great potential for fabrication and investigation of controlled arrangements of nanoscale objects.

Published in:
Applied Physics Letters  (Volume:92 ,  Issue: 2 )

Date of Publication: Jan 2008

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