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High-throughput evaluation of domain switching in piezoelectric ceramics and application to PbZr0.6Ti0.4O3 doped with La and Fe

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3 Author(s)
Jones, Jacob L. ; Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400, USA ; Pramanick, Abhijit ; Daniels, John E.

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A combinatorial material synthesis and characterization technique is introduced and demonstrated wherein the ferroelectric behavior of a compositionally graded bulk ceramic is investigated during electrical loading. Using combined high-energy x-ray microdiffraction and fluorescence spectroscopy, non-180° domain wall motion of different compositions is measured and quantified as a function of composition across the gradation. The greatest amount of non-180° domain wall motion is found in samples containing the highest measured fraction of La dopant (2 mol %).

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Applied Physics Letters  (Volume:93 ,  Issue: 15 )