TaCxNy films were grown by a plasma-enhanced atomic layer deposition using Ta(N-t-C5H11)[N(CH3)2]3 as the precursor and H2 or Ar/H2 plasma as the reducing agent. The Ar/H2 plasma appeared to efficiently break the Ta–N bonds in the Ta precursor and formed more TaCx, which significantly decreased the resistivity of the films (∼255 μΩ cm) compared with the case of the H2 plasma (∼1570 μΩ cm). The Ar/H2 plasma also made the films denser and efficiently eliminated the oxygen from the films. This improved the resistance against the elemental diffusion as well as the aging characteristics of the films after exposure to air.
Published in:
Applied Physics Letters
(Volume:91
,
Issue:
25
)
Date of Publication:
Dec 2007
- Page(s):
-
252106
-
252106-3
- ISSN :
-
0003-6951
- Digital Object Identifier :
-
10.1063/1.2825272
- Product Type:
-
Journals & Magazines
- Date of Current Version :
-
18 June 2009
- Issue Date :
-
Dec 2007