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Epitaxial growth and B-site cation ordering in layered double perovskite La2CuSnO6 thin films

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7 Author(s)
Masuno, A. ; Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan ; Haruta, M. ; Azuma, M. ; Kurata, H.
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Epitaxial thin films of layered double perovskite La2CuSnO6 were fabricated on (001)-oriented SrTiO3, (LaAlO3)0.3–(SrAl0.5Ta0.5O3)0.7, and LaAlO3 substrates with a pulsed laser deposition method. B-site cation ordering of the layer structure can be controlled by tuning the substrate temperature during deposition. X-ray diffraction and scanning transmission electron microscopy revealed that the lattice parameters were strongly correlated with the degree of Cu/Sn ordering. The relationship between the lattice parameters and the B-site cation ordering originates in the orientation of the Jahn-Teller distorted CuO6 octahedra.

Published in:

Applied Physics Letters  (Volume:89 ,  Issue: 21 )

Date of Publication:

Nov 2006

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