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Tuning acceptor energy level for efficient charge collection in copper-phthalocyanine-based organic solar cells

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4 Author(s)
Chu, Chih-Wei ; Department of Materials Science and Engineering, University of California at Los Angeles, Los Angeles, California 90095 ; Shrotriya, Vishal ; Li, Gang ; Yang, Yang

Your organization might have access to this article on the publisher's site. To check, click on this link:http://dx.doi.org/+10.1063/1.2194207 

We compare organic donor/acceptor heterojunction photovoltaic devices based on copper phthalocyanine (CuPc) as the donor and [6,6]-phenyl C60 butyric acid methyl ester (PCBM) or buckminsterfullerene (C60) as the acceptor. The effect of the two acceptors on open-circuit voltage and short-circuit current density is studied. Improved interface properties, optimal energy level matching, and more balanced charge transport are believed to be the reasons for better performance of CuPc/PCBM heterojunction device, in terms of photocurrent and fill factor. The energy conversion efficiency of the devices under AM1.5G solar illumination at 130 mW/cm2 is improved to 1.18%, up from 0.74%.

Published in:
Applied Physics Letters  (Volume:88 ,  Issue: 15 )

Date of Publication: Apr 2006

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