We compare organic donor/acceptor heterojunction photovoltaic devices based on copper phthalocyanine (CuPc) as the donor and [6,6]-phenyl C60 butyric acid methyl ester (PCBM) or buckminsterfullerene (C60) as the acceptor. The effect of the two acceptors on open-circuit voltage and short-circuit current density is studied. Improved interface properties, optimal energy level matching, and more balanced charge transport are believed to be the reasons for better performance of CuPc/PCBM heterojunction device, in terms of photocurrent and fill factor. The energy conversion efficiency of the devices under AM1.5G solar illumination at 130 mW/cm2 is improved to 1.18%, up from 0.74%.
Published in:
Applied Physics Letters
(Volume:88
,
Issue:
15
)
Date of Publication:
Apr 2006
- Page(s):
-
153504
-
153504-3
- ISSN :
-
0003-6951
- Digital Object Identifier :
-
10.1063/1.2194207
- Product Type:
-
Journals & Magazines
- Date of Current Version :
-
18 June 2009
- Issue Date :
-
Apr 2006