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Carbon nanotube composites with high dielectric constant at low percolation threshold

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2 Author(s)
Wang, Lan ; Key Laboratory of Beijing City for Preparation and Processing of Novel Polymer Materials and Key Laboratory of the Ministry of Education on Nanomaterials, Beijing University of Chemical Technology, Beijing 100029, People’s Republic of China ; Dang, Zhi-Min

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In this letter, the dielectric properties of the untreated multiwall carbon-nanotubes/poly(vinylidene fluoride) (MWNT/PVDF) composites are studied. Towards low frequencies, the dielectric constant of a composite with about 2.0 vol % of MWNT increases rapidly and the value of the dielectric constant is as high as 300. However, by a calculation, the percolation threshold of the MWNT/PVDF composites is only 1.61 vol % (0.0161 volume fraction) of MWNT. Both the large aspect ratio and the high conductivity of the MWNT may lead to the low percolation threshold of the MWNT/PVDF composites. For the percolation composite, the dielectric loss value is always less than 0.4, irrespective of the frequency. Therefore, the experimental results suggest that the dielectric properties of MWNT/PVDF composites may be improved significantly without the chemical functionalization to carbon nanotubes.

Published in:

Applied Physics Letters  (Volume:87 ,  Issue: 4 )