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The task allocation is the most important decision of the supply chain strategy. The paper starts from proceeds with the logistic service supply chain (LSSC) collaboration model based on multi-agent system (MAS) to analyze the characteristics of LSSC task allocation. According to the Markov property in the problem, the paper builds a task allocation of LSSC model by using the Markov decision process (MDP). Then, the paper proposes an algorithm based on iterative algorithm for solving the model. The paper provides a reference for studying the task allocation of LSSC quantitatively.