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The location selection of logistics center is an investment decision-making issue with strategic meaning in the national economy mobilization logistics system. Based on correlative literature, this paper establishes the index system of location selection of logistics center, and then constructs the model of location selection of national economy mobilization logistics center based on combination of fuzzy set theory and grey analysis. The ability sequence is determined according to each location's relative approximation. We can select the one which has the highest ability if there are several positions to choose when constructing the mobilization logistics center.