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The synchronization problems are studied for a class of coupling delays networks based on variable structure control. The switching surface is designed by using the left eigenvector function of the system, which can assure the synchronization sliding mode is stability. The hitting condition is used for designing the controller, which can assure the network state globally asymptotically synchronize to the desired orbit in finite time. The example is simulated by using the designed variable structure controller and the simulation results demonstrate the effectiveness of the proposed controllers in this paper.