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This paper carried out the research on the problem of control and synchronization of the chaotic system. The controller based on linear couple rules and the theory of parameters estimation was designed for the continuous-time chaos system with unknown parameter and delayed-time property (CTCS-UP-DTP). Meanwhile, the asymptotic stability of the control and synchronization continuous-time chaos system and the realizable character of unknown parameters estimation would be proved or analyzed in theory. And then the results of simulations illustrated that the given algorithm is valid and effective.