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To investigate the possibilities of using dual-frequency, multipolarization synthetic aperture radar (SAR) data to monitor sea ice, we derived the relationship between various polarization characteristics and the physical parameters of sea ice. We discuss the frequency and polarization characteristics of the backscattering coefficients of sea ice and then characterize its thickness by comparing the corresponding backscattering coefficient for each polarization with the physical parameters of the ice. We first propose a methodology for classifying sea-ice types by using a polarimetric decomposition technique, before comparing an estimation of the sea-ice thickness with the corresponding dual-frequency, multipolarization SAR data. We utilized the backscattering ratio to estimate the thickness of the sea ice. This ratio canceled the effect of roughness on the backscattering. The method was validated using Pi-SAR (polarimetric and interferometric airborne SAR) observation data obtained at ground-truth sites.