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A computationally efficient and accurate physically based gate capacitance model of MOS devices with advanced ultrathin equivalent oxide thickness (EOT) oxides (down to 0.5 nm explicitly considered here) is introduced for the current and near future integrated circuit technology nodes. In such a thin gate dielectric regime, the modeling of quantum-mechanical (QM) effects simply with the assumption of an infinite triangular quantum well at the Si-dielectric interface can result in unacceptable underestimates of calculated gate capacitance. With the aid of self-consistent numerical Schrödinger-Poisson calculations, the QM effects have been reconsidered in this model. The 2/3 power law for the lowest quantized energy level versus field relations (E1∝Fox23/), often used in compact models, was refined to 0.61 for electrons and 0.64 for holes, respectively, in the substrate in the regimes of moderate to strong inversion and accumulation to address primarily barrier penetration. The filling of excited states consistent with Fermi statistics has been addressed. The quantum-corrected gate capacitance-voltage (C-V) calculations have then been tied directly to the Fermi level shift as per the definition of voltage (rather than, for example, obtained indirectly through calculation of quantum corrections to the charge centroids offset from the interface). The model was implemented and tested by comparisons to both numerical calculations down to 0.5 nm, and to experimental data from n-MOS or p-MOS metal-gate devices with SiO2, Si3N4 and high-κ (e.g., HfO2) gate dielectrics on (100) Si with EOTs down to ∼1.3 nm. The compact model has also been adapted to address interface states, and poly depletion and poly accumulation effects on gate capacitance.