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The presheath located near boundaries in weakly ionized plasmas is a rich environment in which charge exchange, and ion-ion streaming instabilities combine to establish the electric fields that accelerate ions to close to the Bohm velocity at the sheath/presheath boundary. Charge exchange sets the presheath scale length in weakly collisional plasma, in which ionization can be neglected. The transition of mobility limited ion flow near the bulk plasma to free fall motion close to the plate for single species plasmas is explored. Measurements in argon-helium multidipole plasmas of plasma potential with emissive probes and ion energy distribution functions with laser induced fluorescence are presented. These data show that the argon ions are speeded up by the presheath electric fields, argon ions are heated, and ion-ion instability is present as ions approach the boundary.