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Study of electron tunnelling through thin polymer films using a mercury probe technique

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4 Author(s)
Nabok, A.V. ; Sch. of Eng., Sheffield Hallam Univ., UK ; Massey, J. ; Buttle, S. ; Ray, A.K.

A non-destructive technique employing a mercury probe as a counter electrode was successfully developed in order to study the mechanism of charge transport through thin polymer films on silicon and aluminum substrates. The polyelectrolyte self-assembly technique was employed to form the organic films. Both DC and AC current-voltage characteristics were measured at room temperature. An exponential dependence of the tunnelling current on the film thickness was found, and a tunnelling coefficient of 3.3×10-9 m-1 was calculated. The observed voltage dependence was interpreted in terms of the model of a trapezoidal-triangular barrier. The peak in current-voltage characteristics of polymer films on aluminum substrates may be attributed to resonance tunnelling via surface states on the alumina/polymer film interface.

Published in:

Circuits, Devices and Systems, IEE Proceedings -  (Volume:151 ,  Issue: 5 )

Date of Publication:

15 Oct. 2004

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