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A 100 Msamples/s 14-bit sampling analog-to-digital converter has been used to perform digital pulse-shape acquisition of signals collected from CHIMERA telescopes. Two different kinds of tests have been carried out to check the performances. The signals from a typical CHIMERA detection cell have been collected using both a standard CHIMERA electronic chain up to the amplifier, and a very simple analog front end, basically reduced to the preamplifier. The obtained on-beam and on-line results are presented.