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As a result of the equivalent series resistor of the boost inductor, conventional boost converters are not able to provide high voltage gain. A high-efficiency high step-up converter is proposed, with low voltage stress on power switch, power diodes and output capacitors. The circuit topology of the proposed converter consists of an energy clamp circuit and a voltage boost cell. The boost converter functions as an active clamp circuit to suppress the voltage spike on power switch during the turn-off transient period. The boost converter output terminal and flyback converter output terminal are serially connected to increase the output voltage gain with the coupled inductor. By serially connecting the secondary windings of the boost inductor, a high voltage gain is achieved with less voltage stress on the power devices, such as power MOSFET and power diodes. The operational principle and steady-state analysis are described. A 35 W converter with simulation and experimental results is presented to demonstrate the performance. It shows that the efficiency of the proposed converter is very high (nearly 93%) with four times the voltage output.