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XML represents a new way of organizing information and knowledge of the World Wide Web. With XML, the concept of "document" is broadened to include an encapsulation of model information in Web-based system modeling and simulation. On the base of analyzing methods of Hybrid System Modeling, XML can be used to design model specification of Hybrid System on the Web: HMXL (Hybrid System Modeling Extensible Language). Meanwhile, a typical hybrid system (such as tank process control system) is modeled using HMXL.