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The growth of electronic commerce (e-commerce) is complex and rapidly expanding. E-commerce is also one of the fastest growing application areas for the World Wide Web, spanning all businesses and industries and providing new paradigms. Computer-based technologies embody essential characteristics of work environments which require many decision making processes. Decision support systems (DSS) allow managers to be more productive in the sense of facilitating more effective and efficient decision making. This work proposes a corporate e-commerce system which is based on DSS and discusses how to design and implement a usable e-commerce system. The system has four components: security module, service module, learning module, and decision making management module. Using an intelligent e-commerce system, such as this one, will enhance the employee's skills and management levels, reduce production costs, promote product sales, and strengthen corporation's market competitiveness effectively.