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Shor and Preskill (see Phys. Rev. Lett., vol.85, p.441, 2000) have provided a simple proof of security of the standard quantum key distribution scheme by Bennett and Brassard (1984) by demonstrating a connection between key distribution and entanglement purification protocols (EPPs) with one-way communications. Here, we provide proofs of security of standard quantum key distribution schemes, Bennett and Brassard and the six-state scheme, against the most general attack, by using the techniques of two-way entanglement purification. We demonstrate clearly the advantage of classical post-processing with two-way classical communications over classical post-processing with only one-way classical communications in quantum key distribution (QKD). This is done by the explicit construction of a new protocol for (the error correction/detection and privacy amplification of) Bennett and Brassard that can tolerate a bit error rate of up to 18.9%, which is higher than what any Bennett and Brassard scheme with only one-way classical communications can possibly tolerate. Moreover, we demonstrate the advantage of the six-state scheme over Bennett and Brassard by showing that the six-state scheme can strictly tolerate a higher bit error rate than Bennett and Brassard. In particular, our six-state protocol can tolerate a bit error rate of 26.4%, which is higher than the upper bound of 25% bit error rate for any secure Bennett and Brassard protocol. Consequently, our protocols may allow higher key generation rate and remain secure over longer distances than previous protocols. Our investigation suggests that two-way entanglement purification is a useful tool in the study of advantage distillation, error correction, and privacy amplification protocols.