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Vibration-vibration energy transfer in the v3mode of CO2

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3 Author(s)
Burak, I. ; Tel-Aviv University, Tel-Aviv, Israel ; Noter, Y. ; Szoke, A.

The vibration-vibration energy transfer of CO2gas initially excited to the first asymmetric stretch level (0001) has been observed. Collisional pumping to the (0111) combination level is measured by monitoring the fluorescence due to the (0111) → (0110) band. The rate constant for the process: CO2(0111) + CO2(0000) → CO2(0001) + CO2(0110) is found to be(5.3 pm 1) times 10^{6}s-1torr-1.

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Quantum Electronics, IEEE Journal of  (Volume:9 ,  Issue: 5 )