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Emission frequencies of the CF4laser

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3 Author(s)
Patterson, C. ; Los Alamos Scientific Lab., Univ. of Calif., Los Alamos, NM, USA ; McDowell, R. ; Nereson, N.

104 (\nu_{2} + \nu_{4}) \leftarrow \nu_{2} hot-band transitions, some of which correspond to known (\nu_{2} + \nu_{4}) \leftarrow \nu_{2} CF4laser lines, have been identified and measured in high-resolution Doppler-limited spectra of12CF4near 16 μm, obtained with a tunable diode laser. From an analysis of these frequencies, the rotational and tensor splitting constants for the ν2vibrational level have been determined. These constants, together with the \nu_{2} + \nu_{4} pump-band spectrum previously obtained, allow the laser emission frequencies for any given CO2pump line to be calculated with an accuracy of 0.01-0.003 cm-1.

Published in:

Quantum Electronics, IEEE Journal of  (Volume:16 ,  Issue: 11 )