X-ray fluorescence as a condition monitoring tool for copper and corrosive sulphur species in insulating oil

Currently there are no standard techniques to detect copper sulphide deposits in transformers to act as an early warning system. This paper develops and tests a procedure using X-Ray Fluorescence (XRF) spectroscopy to tackle this problem and to monitor dissolved copper in oil, which can have a major impact on the dielectric properties of insulating oil. Initially calibration curves for sulphur and copper demonstrate the XRF's limits of quantitation. Subsequently, a laboratory scale sample preparation procedure is developed to demonstrate that corrosive sulphur depletion trends may indirectly monitor copper sulphide formation. To confirm depleting sulphur species are corroding copper samples are analysed with Energy Dispersive XRay spectroscopy. Finally XRF demonstrates that corrosive oil has a low impact on the long term concentration of copper in oil. An XRF condition monitoring technique feasibility study is conducted and recommendations are given in how to implement it in the field.