Thermally robust TaTb/sub x/N metal gate electrode for n-MOSFETs applications

In this letter, we study Terbium (Tb)-incorporated TaN (TaTb/sub x/N) as a thermally robust N-type metal gate electrode for the first time. The work function of the Ta/sub 0.94/Tb/sub 0.06/N/sub y/ metal gate is determined to be /spl sim/4.23 eV after rapid thermal anneal at 1000/spl deg/C for 30 s, and can be further tuned by varying the Tb concentration. Moreover, the TaTb/sub x/N-SiO/sub 2/ gate stack exhibits excellent thermal stability up to 1000/spl deg/C with no degradation to the equivalent oxide thickness, gate leakage, and time-dependent dielectric breakdown (TDDB) characteristics. These results suggest that Tb-incorporated TaN (TaTb/sub x/N) could be a promising metal gate candidate for n-MOSFET in a dual-metal gate Si CMOS process.