Simulated annealing (SA) is a general-purpose optimization technique widely used in various combinatorial optimization problems. However, the main drawback of this technique is a long computation time required to obtain a good quality of solution. Clusters have emerged as a feasible and popular platform for parallel computing in many applications. Computing nodes on many of the clusters available today are temporally heterogeneous. In this study, multiple Markov chain (MMC) parallel simulated annealing (PSA) algorithms have been implemented on a temporally heterogeneous cluster of workstations to solve the graph partitioning problem and their performance has been analyzed in detail. Temporal heterogeneity of a cluster of workstations is harnessed by employing static and dynamic load balancing techniques to further improve efficiency and scalability of the MMC PSA algorithms.