This technical note is concerned with the sampled-data synchronization control problem for a class of dynamical networks. The sampling period considered here is assumed to be time-varying that switches between two different values in a random way with given probability. The addressed synchronization control problem is first formulated as an exponentially mean-square stabilization problem for a new class of dynamical networks that involve both the multiple probabilistic interval delays (MPIDs) and the sector-bounded nonlinearities (SBNs). Then, a novel Lyapunov functional is constructed to obtain sufficient conditions under which the dynamical network is exponentially mean-square stable. Both Gronwall's inequality and Jenson integral inequality are utilized to substantially simplify the derivation of the main results. Subsequently, a set of sampled-data synchronization controllers is designed in terms of the solution to certain matrix inequalities that can be solved effectively by using available software. Finally, a numerical simulation example is employed to show the effectiveness of the proposed sampled-data synchronization control scheme.