Study of space charge accumulation in polyolefins submitted to ac stress

The aim of the present study was to follow space charge formation under ac field (50 Hz) in polyolefins. The thermal step method was used, and charge accumulation was observed in crosslinked polyethylene (XLPE), very low density polyethylene (VLDPE), isotactic polypropylene (PP) and a PE /PP copolymer, the temperature varying from 45 to 90/spl deg/C. It was found that the amount of charge accumulated under ac conditions may reach a maximum value at a given temperature, while the highest space charge was found in the polyolefin with the lowest crystallinity ratio. The conduction current characteristics of XLPE specimens show the existence of traps in the polymer at a level deeper than the potential barrier electrode/dielectric, explaining the accumulation of injected charge in the material. The injection and conduction mechanisms observed were interpreted by Schottky and Poole-Frenkel processes and used to explain the maximum accumulation of charge occurring at certain temperatures.