A Novel Failure Analysis Technique for Semiconductor Packaging by Xenon Difluoride Gas

Defect isolation and failure analysis is a key factor that drive development and manufacturing yield improvements in semiconductor packaging industry. From a manufacturing point of view, ensuring adequate package reliability is becoming more challenging due to increasing packaging complexity and a more pronounced impact from material physical property mismatch among packaging materials and components. The task of isolating defects and finding root cause is further complicated by ever shrinking feature sizes within the device and/or package, already approaching the nanometer range in contemporary semiconductor packages. Conventional failure analysis techniques such as physical cross sectioning or micro-cutting using focused ion beams(FIB) are sometimes no longer sufficient to find these defects. Both physical cross section and FIB are only capable of exposing the defect in two dimensions (x and y directions), which makes pinpointing the defect in depth, i.e., the z direction, extremely difficult when dealing defects with micron and submicron size. Additional complications are many times introduced during conventional sample preparation, which can introduce undesirable artifacts associated with the module and/or device depackaging. These artifacts may mask the true defects, or lead to misinterpretation of the true cause of failure. In this work, it has been determined that a three-dimensional failure analysis method is critical for finding some defects in silicon packages. For example, xenon difluoride (XeF2) has excellent selectivity to silicon and provides efficient material removal by chemical reaction, generating gaseous by-products that can be readily exhausted [1]. Furthermore, XeF2 has very little reaction with non-silicon materials, such as SiO2, and the metals and polymers commonly used in semiconductor devices and packages. This paper reports the application of XeF2 as an effective failure analysis technique to reveal defects in silicon packages. The mechanism of selective reaction between XeF2 and Si is discussed and key design features of the failure analysis tool are presented. The paper also highlights a few case studies which advantageously utilize XeF2 etching to expose defects. XeF2 was especially effective in detecting the source of electrical leakage in 3D packages having Through Silicon Via (TSV) structures. Due to its high etching selectivity to silicon, the leakage area in electrically failing samples was found to be due to damage of the TSV liner (passivation layer material) and further analysis reveals a three dimensional view of the TSV defect. With the addition of XeF2 etching, further characterization of defects by traditional methods such as FIB micro cutting also becomes more practical. The work suggests that a wider application of Si removal via XeF2 can be achieved by combining mechanical milling of bulk silicon followed by a final, low stress, silicon removal by XeF2 etching.