The effect of aromatic and sulfur compounds on partial discharge characteristics of hexadecane

Partial discharge (PD) characteristics of hexadecane were studied in a needle-plane electrode geometry under AC field with a 20 μm tip radius tungsten needle. PD experiments were conducted on samples containing known concentrations of aromatic and corrosive sulfur compounds. Partial discharge inception voltage (PDIV), streamer repetition rates, and phase resolved PD (PRPD) patterns were acquired. Ionization potentials (IP) and electron affinities (EA) of hexadecane and the additives were calculated with density functional theory (DFT) and correlated with the PD characteristics. Low IP and negative EA of the additives relative to hexadecane increased the number of positive and negative streamers initiated, except for additives that contained an electron donating group on the aromatic ring. Low IP and positive EA for polyaromatic hydrocarbons (PAH) and corrosive sulfur compounds decreased the number of negative streamers initiated due to large electron capture cross sections. Copper sulfide particulates caused the greatest changes in PD characteristics as a result of its semi-conductive nature.