Effect of thermal ageing on space charge characteristics in double-layered polyester film

To understand the effect of thermal ageing mechanism on space charge formation and dissipation in double-layered polyester films (PET), the time dependence of space charge characteristics at physical interface and in the bulk of PET films have been investigated. The measurements of space charge characteristics in specimens of different thermal ageing conditions (80 and 130 °C) were conducted under different DC field strengths (polarization) and short circuit conditions (depolarization) using the Pulsed Electro Acoustic (PEA) measurement system. The influence of electric field distortion caused by the space charges on average AC breakdown strength of PET specimens was also investigated. Results indicate that the thermal ageing leads to polymer interface acts as positive charge traps at ageing temperature of 80 °C, but acts as electron traps at ageing temperature of 130 °C and provides deeper trapping level for positive charge carriers. Besides these, average breakdown strength of the composite decreases due to the electric field distortion caused by the space charges. A preliminary study of this phenomenon is given and further investigation is needed.