Are Lithium Ion Cells Intrinsically Safe?

National Institute for Occupational Safety and Health researchers are studying the potential for Li-ion-battery thermal runaway from an internal short circuit in equipment approved as permissible for use in underground coal mines. Researchers used a plastic wedge to induce internal short circuits for thermal runaway susceptibility evaluation purposes, which proved to be a more severe test than the flat plate method for selected Li-ion cells. Researchers conducted cell crush tests within a 20-L chamber filled with 6.5
$\%$

$\hbox{CH}_{4}$
–air to simulate the mining hazard. Results indicate that LG Chem ICR18650S2
$\hbox{LiCoO}_{2}$
cells pose a
$\hbox{CH}_{4}$
explosion hazard from a cell internal short circuit. Under specified test conditions, A123 Systems 26650
$\hbox{LiFePO}_{4}$
cells were safer than the LG Chem ICR18650S2
$\hbox{LiCoO}_{2}$
cells at a conservative statistical significance level.